Electrochemical double layer capacitor performance of electrospun polymer fiber-electrolyte membrane fabricated by solvent-assisted and thermally induced compression molding processes

► Polymer electrolyte membranes were fabricated by compression of electrospun fibers. ► Polymer electrolyte membranes exhibit a free-standing shape with bending capability. ► SPEs showed good performances compared with the liquid organic electrolyte. The electrochemical characteristics of electric d...

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Veröffentlicht in:Journal of membrane science 2012-08, Vol.409-410, p.365-370
Hauptverfasser: Lee, Pyoung-Chan, Han, Tai-Hoon, Hwang, Taeseon, Oh, Joon-Suk, Kim, Se-Joon, Kim, Byung-Woo, Lee, Youngkwan, Choi, Hyouk Ryeol, Jeoung, Sun Kyoung, Yoo, Seung Eul, Nam, Jae-Do
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container_end_page 370
container_issue
container_start_page 365
container_title Journal of membrane science
container_volume 409-410
creator Lee, Pyoung-Chan
Han, Tai-Hoon
Hwang, Taeseon
Oh, Joon-Suk
Kim, Se-Joon
Kim, Byung-Woo
Lee, Youngkwan
Choi, Hyouk Ryeol
Jeoung, Sun Kyoung
Yoo, Seung Eul
Nam, Jae-Do
description ► Polymer electrolyte membranes were fabricated by compression of electrospun fibers. ► Polymer electrolyte membranes exhibit a free-standing shape with bending capability. ► SPEs showed good performances compared with the liquid organic electrolyte. The electrochemical characteristics of electric double layer capacitors composed of solid polymer electrolytes with different thicknesses were investigated. A solid polymer electrolyte membrane was fabricated using electrospun fibers through solvent-assisted or thermally induced compression molding. Through the solvent-assisted or thermally induced compression molding processes, the poly(acrylonitrile) (PAN) microfibers consolidated together by the interlocking of the fibers under compression. A solid polymer electrolyte membrane clearly exhibited a free-standing shape with a bending capability. The electrospun PAN non-woven fabric and electrolyte salt composites showed higher ionic conductivity (>10−3Scm−1 at 298K) and capacitance compared with the liquid organic electrolyte. The solid polymer electrolytes provided a 10.6% increase in the energy density, seemingly due to the decrease in the IR drop and increase in the capacitance.
doi_str_mv 10.1016/j.memsci.2012.04.007
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subjects artificial membranes
capacitance
Compression molding
Electric double layer capacitors
electrical equipment
electrochemistry
electrolytes
Electrospinning
energy density
Poly(acrylonitrile)
polymers
Solid polymer electrolytes
title Electrochemical double layer capacitor performance of electrospun polymer fiber-electrolyte membrane fabricated by solvent-assisted and thermally induced compression molding processes
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