Electrochemical double layer capacitor performance of electrospun polymer fiber-electrolyte membrane fabricated by solvent-assisted and thermally induced compression molding processes
► Polymer electrolyte membranes were fabricated by compression of electrospun fibers. ► Polymer electrolyte membranes exhibit a free-standing shape with bending capability. ► SPEs showed good performances compared with the liquid organic electrolyte. The electrochemical characteristics of electric d...
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Veröffentlicht in: | Journal of membrane science 2012-08, Vol.409-410, p.365-370 |
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container_title | Journal of membrane science |
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creator | Lee, Pyoung-Chan Han, Tai-Hoon Hwang, Taeseon Oh, Joon-Suk Kim, Se-Joon Kim, Byung-Woo Lee, Youngkwan Choi, Hyouk Ryeol Jeoung, Sun Kyoung Yoo, Seung Eul Nam, Jae-Do |
description | ► Polymer electrolyte membranes were fabricated by compression of electrospun fibers. ► Polymer electrolyte membranes exhibit a free-standing shape with bending capability. ► SPEs showed good performances compared with the liquid organic electrolyte.
The electrochemical characteristics of electric double layer capacitors composed of solid polymer electrolytes with different thicknesses were investigated. A solid polymer electrolyte membrane was fabricated using electrospun fibers through solvent-assisted or thermally induced compression molding. Through the solvent-assisted or thermally induced compression molding processes, the poly(acrylonitrile) (PAN) microfibers consolidated together by the interlocking of the fibers under compression. A solid polymer electrolyte membrane clearly exhibited a free-standing shape with a bending capability. The electrospun PAN non-woven fabric and electrolyte salt composites showed higher ionic conductivity (>10−3Scm−1 at 298K) and capacitance compared with the liquid organic electrolyte. The solid polymer electrolytes provided a 10.6% increase in the energy density, seemingly due to the decrease in the IR drop and increase in the capacitance. |
doi_str_mv | 10.1016/j.memsci.2012.04.007 |
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The electrochemical characteristics of electric double layer capacitors composed of solid polymer electrolytes with different thicknesses were investigated. A solid polymer electrolyte membrane was fabricated using electrospun fibers through solvent-assisted or thermally induced compression molding. Through the solvent-assisted or thermally induced compression molding processes, the poly(acrylonitrile) (PAN) microfibers consolidated together by the interlocking of the fibers under compression. A solid polymer electrolyte membrane clearly exhibited a free-standing shape with a bending capability. The electrospun PAN non-woven fabric and electrolyte salt composites showed higher ionic conductivity (>10−3Scm−1 at 298K) and capacitance compared with the liquid organic electrolyte. The solid polymer electrolytes provided a 10.6% increase in the energy density, seemingly due to the decrease in the IR drop and increase in the capacitance.</description><identifier>ISSN: 0376-7388</identifier><identifier>EISSN: 1873-3123</identifier><identifier>DOI: 10.1016/j.memsci.2012.04.007</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>artificial membranes ; capacitance ; Compression molding ; Electric double layer capacitors ; electrical equipment ; electrochemistry ; electrolytes ; Electrospinning ; energy density ; Poly(acrylonitrile) ; polymers ; Solid polymer electrolytes</subject><ispartof>Journal of membrane science, 2012-08, Vol.409-410, p.365-370</ispartof><rights>2012 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-676565077f0d2677ad10bdeec507f5e14042e3335d1958889d6818789ac4cc193</citedby><cites>FETCH-LOGICAL-c363t-676565077f0d2677ad10bdeec507f5e14042e3335d1958889d6818789ac4cc193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.memsci.2012.04.007$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Lee, Pyoung-Chan</creatorcontrib><creatorcontrib>Han, Tai-Hoon</creatorcontrib><creatorcontrib>Hwang, Taeseon</creatorcontrib><creatorcontrib>Oh, Joon-Suk</creatorcontrib><creatorcontrib>Kim, Se-Joon</creatorcontrib><creatorcontrib>Kim, Byung-Woo</creatorcontrib><creatorcontrib>Lee, Youngkwan</creatorcontrib><creatorcontrib>Choi, Hyouk Ryeol</creatorcontrib><creatorcontrib>Jeoung, Sun Kyoung</creatorcontrib><creatorcontrib>Yoo, Seung Eul</creatorcontrib><creatorcontrib>Nam, Jae-Do</creatorcontrib><title>Electrochemical double layer capacitor performance of electrospun polymer fiber-electrolyte membrane fabricated by solvent-assisted and thermally induced compression molding processes</title><title>Journal of membrane science</title><description>► Polymer electrolyte membranes were fabricated by compression of electrospun fibers. ► Polymer electrolyte membranes exhibit a free-standing shape with bending capability. ► SPEs showed good performances compared with the liquid organic electrolyte.
The electrochemical characteristics of electric double layer capacitors composed of solid polymer electrolytes with different thicknesses were investigated. A solid polymer electrolyte membrane was fabricated using electrospun fibers through solvent-assisted or thermally induced compression molding. Through the solvent-assisted or thermally induced compression molding processes, the poly(acrylonitrile) (PAN) microfibers consolidated together by the interlocking of the fibers under compression. A solid polymer electrolyte membrane clearly exhibited a free-standing shape with a bending capability. The electrospun PAN non-woven fabric and electrolyte salt composites showed higher ionic conductivity (>10−3Scm−1 at 298K) and capacitance compared with the liquid organic electrolyte. The solid polymer electrolytes provided a 10.6% increase in the energy density, seemingly due to the decrease in the IR drop and increase in the capacitance.</description><subject>artificial membranes</subject><subject>capacitance</subject><subject>Compression molding</subject><subject>Electric double layer capacitors</subject><subject>electrical equipment</subject><subject>electrochemistry</subject><subject>electrolytes</subject><subject>Electrospinning</subject><subject>energy density</subject><subject>Poly(acrylonitrile)</subject><subject>polymers</subject><subject>Solid polymer electrolytes</subject><issn>0376-7388</issn><issn>1873-3123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kc1u1TAQhSMEEpfCGyDhJZuk4ziJnQ0SqgpUqsQCurYce9L6yomDnVTKk_F6zFW6ZmXp-JszP6coPnKoOPDu-lxNOGXrqxp4XUFTAchXxYkrKUrBa_G6OIGQXSmFUm-LdzmfAbgE1Z-Kv7cB7ZqifcLJWxOYi9sQkAWzY2LWLMb6NSa2YBpjmsxskcWR4VGVl21mSwz7RPDoB0zly0_YV2Q01ZDMjGw0QyL3FR0bdpZjeMZ5LU3OPl80Mzu2PiHZh7AzP7vNkmrjtCQkJs5sisH5-ZEtNClJmN8Xb0YTMn54ea-Kh2-3v29-lPc_v9_dfL0vrejEWnaya7sWpBzB1Z2UxnEYHKIlbWyRN9DUKIRoHe9bpVTvOkVnU72xjbW8F1fF58OXOv_ZMK968tliCLRW3LLmXHKlalFf0OZALR0mJxz1kvxk0q456EtO-qyPnPQlJw2Nppyo7NNRNpqozWPyWT_8IqADANXUtSLiy0EgLfrsMWnyQErC-UTH1i76_7f4ByWnrMg</recordid><startdate>20120801</startdate><enddate>20120801</enddate><creator>Lee, Pyoung-Chan</creator><creator>Han, Tai-Hoon</creator><creator>Hwang, Taeseon</creator><creator>Oh, Joon-Suk</creator><creator>Kim, Se-Joon</creator><creator>Kim, Byung-Woo</creator><creator>Lee, Youngkwan</creator><creator>Choi, Hyouk Ryeol</creator><creator>Jeoung, Sun Kyoung</creator><creator>Yoo, Seung Eul</creator><creator>Nam, Jae-Do</creator><general>Elsevier B.V</general><scope>FBQ</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope></search><sort><creationdate>20120801</creationdate><title>Electrochemical double layer capacitor performance of electrospun polymer fiber-electrolyte membrane fabricated by solvent-assisted and thermally induced compression molding processes</title><author>Lee, Pyoung-Chan ; Han, Tai-Hoon ; Hwang, Taeseon ; Oh, Joon-Suk ; Kim, Se-Joon ; Kim, Byung-Woo ; Lee, Youngkwan ; Choi, Hyouk Ryeol ; Jeoung, Sun Kyoung ; Yoo, Seung Eul ; Nam, Jae-Do</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-676565077f0d2677ad10bdeec507f5e14042e3335d1958889d6818789ac4cc193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>artificial membranes</topic><topic>capacitance</topic><topic>Compression molding</topic><topic>Electric double layer capacitors</topic><topic>electrical equipment</topic><topic>electrochemistry</topic><topic>electrolytes</topic><topic>Electrospinning</topic><topic>energy density</topic><topic>Poly(acrylonitrile)</topic><topic>polymers</topic><topic>Solid polymer electrolytes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee, Pyoung-Chan</creatorcontrib><creatorcontrib>Han, Tai-Hoon</creatorcontrib><creatorcontrib>Hwang, Taeseon</creatorcontrib><creatorcontrib>Oh, Joon-Suk</creatorcontrib><creatorcontrib>Kim, Se-Joon</creatorcontrib><creatorcontrib>Kim, Byung-Woo</creatorcontrib><creatorcontrib>Lee, Youngkwan</creatorcontrib><creatorcontrib>Choi, Hyouk Ryeol</creatorcontrib><creatorcontrib>Jeoung, Sun Kyoung</creatorcontrib><creatorcontrib>Yoo, Seung Eul</creatorcontrib><creatorcontrib>Nam, Jae-Do</creatorcontrib><collection>AGRIS</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Journal of membrane science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee, Pyoung-Chan</au><au>Han, Tai-Hoon</au><au>Hwang, Taeseon</au><au>Oh, Joon-Suk</au><au>Kim, Se-Joon</au><au>Kim, Byung-Woo</au><au>Lee, Youngkwan</au><au>Choi, Hyouk Ryeol</au><au>Jeoung, Sun Kyoung</au><au>Yoo, Seung Eul</au><au>Nam, Jae-Do</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical double layer capacitor performance of electrospun polymer fiber-electrolyte membrane fabricated by solvent-assisted and thermally induced compression molding processes</atitle><jtitle>Journal of membrane science</jtitle><date>2012-08-01</date><risdate>2012</risdate><volume>409-410</volume><spage>365</spage><epage>370</epage><pages>365-370</pages><issn>0376-7388</issn><eissn>1873-3123</eissn><abstract>► Polymer electrolyte membranes were fabricated by compression of electrospun fibers. ► Polymer electrolyte membranes exhibit a free-standing shape with bending capability. ► SPEs showed good performances compared with the liquid organic electrolyte.
The electrochemical characteristics of electric double layer capacitors composed of solid polymer electrolytes with different thicknesses were investigated. A solid polymer electrolyte membrane was fabricated using electrospun fibers through solvent-assisted or thermally induced compression molding. Through the solvent-assisted or thermally induced compression molding processes, the poly(acrylonitrile) (PAN) microfibers consolidated together by the interlocking of the fibers under compression. A solid polymer electrolyte membrane clearly exhibited a free-standing shape with a bending capability. The electrospun PAN non-woven fabric and electrolyte salt composites showed higher ionic conductivity (>10−3Scm−1 at 298K) and capacitance compared with the liquid organic electrolyte. The solid polymer electrolytes provided a 10.6% increase in the energy density, seemingly due to the decrease in the IR drop and increase in the capacitance.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.memsci.2012.04.007</doi><tpages>6</tpages></addata></record> |
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subjects | artificial membranes capacitance Compression molding Electric double layer capacitors electrical equipment electrochemistry electrolytes Electrospinning energy density Poly(acrylonitrile) polymers Solid polymer electrolytes |
title | Electrochemical double layer capacitor performance of electrospun polymer fiber-electrolyte membrane fabricated by solvent-assisted and thermally induced compression molding processes |
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