Catalytic removal of carbon monoxide over carbon supported palladium catalyst

► Carbon supported palladium (Pd/C) catalyst was prepared. ► Catalytic removal of CO over Pd/C catalyst was studied under dynamic conditions. ► Effects of Pd %, CO conc., humidity, GHSV and reaction environment were studied. Carbon supported palladium (Pd/C) catalyst was prepared by impregnation of...

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Veröffentlicht in:Journal of hazardous materials 2012-11, Vol.241-242, p.463-471
Hauptverfasser: Srivastava, Avanish Kumar, Saxena, Amit, Shah, Dilip, Mahato, T.H., Singh, Beer, Shrivastava, A.R., Gutch, P.K., Shinde, C.P.
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Sprache:eng
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Zusammenfassung:► Carbon supported palladium (Pd/C) catalyst was prepared. ► Catalytic removal of CO over Pd/C catalyst was studied under dynamic conditions. ► Effects of Pd %, CO conc., humidity, GHSV and reaction environment were studied. Carbon supported palladium (Pd/C) catalyst was prepared by impregnation of palladium chloride using incipient wetness technique, which was followed by liquid phase reduction with formaldehyde. Thereafter, Pd/C catalyst was characterized using X-ray diffractometery, scanning electron microscopy, atomic absorption spectroscopy, thermo gravimetry, differential scanning calorimetry and surface characterization techniques. Catalytic removal of carbon monoxide (CO) over Pd/C catalyst was studied under dynamic conditions. Pd/C catalyst was found to be continuously converting CO to CO2 through the catalyzed reaction, i.e., CO+1/2O2→CO2. Pd/C catalyst provided excellent protection against CO. Effects of palladium wt%, CO concentration, humidity, space velocity and reaction environment were also studied on the breakthrough behavior of CO.
ISSN:0304-3894
1873-3336
DOI:10.1016/j.jhazmat.2012.10.001