Influence of local structure on magnetic properties of layered cobaltites PrBaCo2O(5+δ), δ > 0.5
The effect of local structure on the magnetic and transport properties of the layered perovskites has been investigated. The samples PrBaCo(2)O(5+δ), (δ = 0.80 and 0.67) crystallize in the same 112 type tetragonal structure but have different magnetic ground states. Extended x-ray absorption fine st...
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Veröffentlicht in: | Journal of physics. Condensed matter 2012-11, Vol.24 (47), p.476003-476003 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The effect of local structure on the magnetic and transport properties of the layered perovskites has been investigated. The samples PrBaCo(2)O(5+δ), (δ = 0.80 and 0.67) crystallize in the same 112 type tetragonal structure but have different magnetic ground states. Extended x-ray absorption fine structure (EXAFS) spectroscopy has been employed to explain the changes in magnetic interactions based on the rotation and tilting of CoO polyhedra in these oxygen-rich double perovskites. |
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ISSN: | 1361-648X |
DOI: | 10.1088/0953-8984/24/47/476003 |