Structure and properties of linear polyethylene-montmorillonite nanocomposites

Nanocomposites based on PE and three types of montmorillonite are prepared by melt blending on a Brabender plastograph. The structure of hybrid materials is studied with the use of X-ray diffraction analysis and transmission electron microscopy. The type of modifier and the polarity of the polyolefin matrix affect the character of the filler structure (intercalated and exfoliated) formed during blending with the polymer. A correlation is found between the parameters of structural organization and the mechanical and barrier properties of nanocomposites. The tensile modulus of the nanocomposites containing 3–5 wt % modified montmorillonite is 75% higher than that of the unfilled PE, whereas the time of combustion and the rate of flame propagation are 20 and 10% smaller, respectively.