Picking up 30 CO2 Molecules by a Porous Metal Oxide Capsule Based on the Same Number of Receptors

Picking up 30 CO2 Molecules by a Porous Metal Oxide Capsule Based on the Same Number of Receptors

30 receptors in waiting position: In the porous (pentagon)12(linker)30‐type molybdenum oxide capsule (see picture), the 30 positively charged linkers (five unsaturated shown for illustration in green, the others contain CO32− ligands) can act as receptors for neutral and negatively charged ligands....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2012-10, Vol.51 (42), p.10528-10531
Hauptverfasser: Garai, Somenath, Haupt, Erhard T. K., Bögge, Hartmut, Merca, Alice, Müller, Achim
Format: Artikel
Sprache:eng
Schlagworte:
carbon dioxide fixation
confined conditions
molecular recognition
polyoxometalates
porous capsules
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:30 receptors in waiting position: In the porous (pentagon)12(linker)30‐type molybdenum oxide capsule (see picture), the 30 positively charged linkers (five unsaturated shown for illustration in green, the others contain CO32− ligands) can act as receptors for neutral and negatively charged ligands. Bubbling CO2 into the solution containing the acetate‐type capsules leads to the upload of CO2 based on 30 coordinated CO32− ligands.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201204089