One-Pot Functionalization of Graphene with Porphyrin through Cycloaddition Reactions
Two types of graphene‐based hybrid materials, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions. The hybrid materials were characterized by thermogravimetric analysi...
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| Veröffentlicht in: | Chemistry : a European journal 2011-08, Vol.17 (32), p.8957-8964 |
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| container_title | Chemistry : a European journal |
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| creator | Zhang, Xiaoyan Hou, Lili Cnossen, Arjen Coleman, Anthony C. Ivashenko, Oleksii Rudolf, Petra van Wees, Bart J. Browne, Wesley R. Feringa, Ben L. |
| description | Two types of graphene‐based hybrid materials, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions. The hybrid materials were characterized by thermogravimetric analysis (TGA), by TEM, by UV/Vis, FTIR, Raman, and luminescence spectroscopy, and by fluorescence/phosphorescence lifetime measurements. The presence of the covalent linkages between graphene and porphyrin was confirmed by FTIR and Raman spectroscopy and further supported by control experiments. The presence of TPP (or PdTPP) in the hybrid material was demonstrated by UV/Vis spectroscopy, with TGA results indicating that the graphene‐TPP and graphene‐PdTPP hybrid materials contained approximately 18 % TPP and 20 % PdTPP. The quenching of fluorescence (or phosphorescence) and reduced lifetimes suggest excited state energy/electron transfer between graphene and the covalently attached TPP (or PdTPP) molecules.
Photoactive units on graphene: Two types of graphene‐based hybrid material, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions (see scheme). In view of the unique properties of both graphene and porphyrin, these two hybrid materials might have potential applications in a number of areas, such as solar cells and sensors. |
| doi_str_mv | 10.1002/chem.201100980 |
| format | Article |
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Photoactive units on graphene: Two types of graphene‐based hybrid material, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions (see scheme). In view of the unique properties of both graphene and porphyrin, these two hybrid materials might have potential applications in a number of areas, such as solar cells and sensors.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201100980</identifier><identifier>PMID: 21735500</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Chemistry ; cycloaddition ; graphene ; luminescence ; porphyrin ; Raman spectroscopy ; Spectrum analysis</subject><ispartof>Chemistry : a European journal, 2011-08, Vol.17 (32), p.8957-8964</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4110-18e6f5d7ddb79f3e47e5373c71bcbbcc3e5ae0ff49823a267e1df8f6db69f5233</citedby><cites>FETCH-LOGICAL-c4110-18e6f5d7ddb79f3e47e5373c71bcbbcc3e5ae0ff49823a267e1df8f6db69f5233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201100980$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201100980$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21735500$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Xiaoyan</creatorcontrib><creatorcontrib>Hou, Lili</creatorcontrib><creatorcontrib>Cnossen, Arjen</creatorcontrib><creatorcontrib>Coleman, Anthony C.</creatorcontrib><creatorcontrib>Ivashenko, Oleksii</creatorcontrib><creatorcontrib>Rudolf, Petra</creatorcontrib><creatorcontrib>van Wees, Bart J.</creatorcontrib><creatorcontrib>Browne, Wesley R.</creatorcontrib><creatorcontrib>Feringa, Ben L.</creatorcontrib><title>One-Pot Functionalization of Graphene with Porphyrin through Cycloaddition Reactions</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>Two types of graphene‐based hybrid materials, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions. The hybrid materials were characterized by thermogravimetric analysis (TGA), by TEM, by UV/Vis, FTIR, Raman, and luminescence spectroscopy, and by fluorescence/phosphorescence lifetime measurements. The presence of the covalent linkages between graphene and porphyrin was confirmed by FTIR and Raman spectroscopy and further supported by control experiments. The presence of TPP (or PdTPP) in the hybrid material was demonstrated by UV/Vis spectroscopy, with TGA results indicating that the graphene‐TPP and graphene‐PdTPP hybrid materials contained approximately 18 % TPP and 20 % PdTPP. The quenching of fluorescence (or phosphorescence) and reduced lifetimes suggest excited state energy/electron transfer between graphene and the covalently attached TPP (or PdTPP) molecules.
Photoactive units on graphene: Two types of graphene‐based hybrid material, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions (see scheme). In view of the unique properties of both graphene and porphyrin, these two hybrid materials might have potential applications in a number of areas, such as solar cells and sensors.</description><subject>Chemistry</subject><subject>cycloaddition</subject><subject>graphene</subject><subject>luminescence</subject><subject>porphyrin</subject><subject>Raman spectroscopy</subject><subject>Spectrum analysis</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkM9v0zAYhi0EYmVw5YgiceGS4h-1HR8h2rpJg1WoaEfLcT4TjzTu7ESj_PVz11EhLpz8WXreR9_3IvSW4DnBmH60HWzmFJP8URV-hmaEU1IyKfhzNMNqIUvBmTpBr1K6xZkRjL1EJ5RIxjnGM7S-HqBchbE4nwY7-jCY3v82-6EIrlhGs-1ggOLej12xCnHb7aIfirGLYfrRFfXO9sG0rX8MfAPzqEiv0Qtn-gRvnt5T9P38bF1flFfXy8v601VpF3nhklQgHG9l2zZSOQYLCZxJZiVpbNNYy4AbwM4tVEWZoUICaV3lRNsI5Thl7BR9OHi3MdxNkEa98clC35sBwpQ0wYrlK1nFM_r-H_Q2TDFfmykphCCUUJWp-YGyMaQUwelt9BsTd1ml933rfd_62HcOvHvSTs0G2iP-p-AMqANw73vY_Uen64uzL3_Ly0PWpxF-HbMm_tRCMsn1zdel5jfrz_VKrvSSPQC6C5wm</recordid><startdate>20110801</startdate><enddate>20110801</enddate><creator>Zhang, Xiaoyan</creator><creator>Hou, Lili</creator><creator>Cnossen, Arjen</creator><creator>Coleman, Anthony C.</creator><creator>Ivashenko, Oleksii</creator><creator>Rudolf, Petra</creator><creator>van Wees, Bart J.</creator><creator>Browne, Wesley R.</creator><creator>Feringa, Ben L.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20110801</creationdate><title>One-Pot Functionalization of Graphene with Porphyrin through Cycloaddition Reactions</title><author>Zhang, Xiaoyan ; Hou, Lili ; Cnossen, Arjen ; Coleman, Anthony C. ; Ivashenko, Oleksii ; Rudolf, Petra ; van Wees, Bart J. ; Browne, Wesley R. ; Feringa, Ben L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4110-18e6f5d7ddb79f3e47e5373c71bcbbcc3e5ae0ff49823a267e1df8f6db69f5233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>cycloaddition</topic><topic>graphene</topic><topic>luminescence</topic><topic>porphyrin</topic><topic>Raman spectroscopy</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xiaoyan</creatorcontrib><creatorcontrib>Hou, Lili</creatorcontrib><creatorcontrib>Cnossen, Arjen</creatorcontrib><creatorcontrib>Coleman, Anthony C.</creatorcontrib><creatorcontrib>Ivashenko, Oleksii</creatorcontrib><creatorcontrib>Rudolf, Petra</creatorcontrib><creatorcontrib>van Wees, Bart J.</creatorcontrib><creatorcontrib>Browne, Wesley R.</creatorcontrib><creatorcontrib>Feringa, Ben L.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xiaoyan</au><au>Hou, Lili</au><au>Cnossen, Arjen</au><au>Coleman, Anthony C.</au><au>Ivashenko, Oleksii</au><au>Rudolf, Petra</au><au>van Wees, Bart J.</au><au>Browne, Wesley R.</au><au>Feringa, Ben L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-Pot Functionalization of Graphene with Porphyrin through Cycloaddition Reactions</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2011-08-01</date><risdate>2011</risdate><volume>17</volume><issue>32</issue><spage>8957</spage><epage>8964</epage><pages>8957-8964</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>Two types of graphene‐based hybrid materials, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions. The hybrid materials were characterized by thermogravimetric analysis (TGA), by TEM, by UV/Vis, FTIR, Raman, and luminescence spectroscopy, and by fluorescence/phosphorescence lifetime measurements. The presence of the covalent linkages between graphene and porphyrin was confirmed by FTIR and Raman spectroscopy and further supported by control experiments. The presence of TPP (or PdTPP) in the hybrid material was demonstrated by UV/Vis spectroscopy, with TGA results indicating that the graphene‐TPP and graphene‐PdTPP hybrid materials contained approximately 18 % TPP and 20 % PdTPP. The quenching of fluorescence (or phosphorescence) and reduced lifetimes suggest excited state energy/electron transfer between graphene and the covalently attached TPP (or PdTPP) molecules.
Photoactive units on graphene: Two types of graphene‐based hybrid material, graphene‐TPP (TPP=tetraphenylporphyrin) and graphene‐PdTPP (PdTPP=palladium tetraphenylporphyrin), were prepared directly from pristine graphene through one‐pot cycloaddition reactions (see scheme). In view of the unique properties of both graphene and porphyrin, these two hybrid materials might have potential applications in a number of areas, such as solar cells and sensors.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21735500</pmid><doi>10.1002/chem.201100980</doi><tpages>8</tpages></addata></record> |
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| subjects | Chemistry cycloaddition graphene luminescence porphyrin Raman spectroscopy Spectrum analysis |
| title | One-Pot Functionalization of Graphene with Porphyrin through Cycloaddition Reactions |
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