Length and time scales of structural heterogeneities in deeply supercooled propylene carbonate

Deactivation of excited phenanthrene by molecular oxygen is utilized to probe the structural heterogeneity of supercooled propylene carbonate. The diffusion rate of oxygen molecules in different regions varies over two orders of magnitude. The size of the regions of different oxygen mobility was determined to be 1.5 nm. Values from 0.2 to 30 s have been obtained for the lifetime of these regions over a temperature range from T(g)-1 to T(g)+4 K (T(g)=158 K). The heterogeneity lifetime is in close agreement with the α-relaxation time determined by dielectric spectroscopy. The obtained results argue in favor of the statement that the heterogeneous cooperative dynamics of host molecules (so-called dynamical heterogeneity) is of structural origin.