Hexagonal prismatic dodecameric water cluster: a building unit of the five-fold interpenetrating six-connected supramolecular network

Hexagonal prismatic dodecameric water cluster: a building unit of the five-fold interpenetrating six-connected supramolecular network

An experimental (H(2)O)(n) (n > 10) aggregate, similar to a theoretical hexagonal prismatic dodecameric water cluster structure, is characterized, the water cluster can be reversibly generated. The hydrogen bonds between the water clusters and bis(imidazolyl) ligand result in the formation of a f...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (72), p.9014-9016
Hauptverfasser: Li, Xiaoju, Xu, Xiahong, Yuan, Daqiang, Weng, Xiulan
Format: Artikel
Sprache:eng
Schlagworte:
Aggregates
Clusters
Hydrogen Bonding
Hydrogen bonds
Interpenetrating networks
Ligands
Models, Molecular
Molecular Conformation
Polymers - chemistry
Water - chemistry
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Zusammenfassung:An experimental (H(2)O)(n) (n > 10) aggregate, similar to a theoretical hexagonal prismatic dodecameric water cluster structure, is characterized, the water cluster can be reversibly generated. The hydrogen bonds between the water clusters and bis(imidazolyl) ligand result in the formation of a five-fold interpenetrating six-connected supramolecular network.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc34412b