(Acetylacetonato-κ2O,O′)[1-(4-bromophenyl-κC2)-3-methylimidazol-2-ylidene-κC2]platinum(II)

(Acetylacetonato-κ2O,O′)[1-(4-bromophenyl-κC2)-3-methylimidazol-2-ylidene-κC2]platinum(II)

The title platinum(II) complex, [Pt(C10H8BrN2)(C5H7O2)], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square‐planar coordination environment around the PtII centre. In the solid state, the molecules are oriented in a par...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2012-08, Vol.68 (8), p.m203-m205
Hauptverfasser: Tenne, Mario, Unger, Yvonne, Strassner, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
Crystal structure
Crystallography
Distortion
Hydrogen bonding
Ligands
Solid state
Spectators
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Zusammenfassung:The title platinum(II) complex, [Pt(C10H8BrN2)(C5H7O2)], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square‐planar coordination environment around the PtII centre. In the solid state, the molecules are oriented in a parallel fashion by intermolecular hydrogen bonding and π–π and C—H...π interactions, while close Pt...Pt contacts are not observed. The structure is only the second example for this new class of compounds.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270112027783