Laser operated elasto-optical features of La2CaB10O19:Pr3+ polymer nanocomposites

We have discovered a principal role of the polymer matrices on the spectral dependences of piezooptical coefficients of La2CaB10O19:Pr3+ (LCBO:Pr) nanocomposites formed by polymethylmethacrylate (PMMA) and polycarbonate (PC) matrices. It was established that the optical treatment by the 10ns Nd:YAG...

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Veröffentlicht in:Journal of luminescence 2012-10, Vol.132 (10), p.2577-2580
Hauptverfasser: Majchrowski, A., Lakshminarayana, G., Reshak, A.H., Michalski, E., Olifierczuk, M., Ozga, K., Jaroszewicz, L., Lukasiewicz, T., Szota, M., Nabialek, M.
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Sprache:eng
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Zusammenfassung:We have discovered a principal role of the polymer matrices on the spectral dependences of piezooptical coefficients of La2CaB10O19:Pr3+ (LCBO:Pr) nanocomposites formed by polymethylmethacrylate (PMMA) and polycarbonate (PC) matrices. It was established that the optical treatment by the 10ns Nd:YAG laser can cause substantial changes of the dispersion of the piezooptical coefficients within the spectral wavelength 1400–1600nm. The optimal content of the LCBO:Pr with sizes ranging from 40 to 110nm corresponds to 4–6% in weighing units. Following the performed quantum chemical simulations, the observed changes are caused by different polarizabilities of the polymer matrices. ► Spectral dependences of piezooptical coefficients of La2CaB10O19:Pr3+ nanocomposites were studied. ► Substantial enhancement of the piezooptical dispersion was observed within the spectral range 1440–1520nm. ► The observed changes are caused by different polarizabilities of the polymer matrices.
ISSN:0022-2313
1872-7883
DOI:10.1016/j.jlumin.2012.04.042