Sulfate-templated self-assembly of new M4L6 tetrahedral metal organic cages

Six equivalents of N,N'-bis(4-aminobenzyl)urea, 12 equivalents of 2-formylpyridine and four equivalents of FeSO(4) or NiSO(4) undergo subcomponent self-assembly in aqueous solution to form tetrahedral cages around a single, encapsulated sulfate anion.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-10, Vol.48 (83), p.10295-10297
Hauptverfasser: Yi, Song, Brega, Valentina, Captain, Burjor, Kaifer, Angel E
Format: Artikel
Sprache:eng
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Zusammenfassung:Six equivalents of N,N'-bis(4-aminobenzyl)urea, 12 equivalents of 2-formylpyridine and four equivalents of FeSO(4) or NiSO(4) undergo subcomponent self-assembly in aqueous solution to form tetrahedral cages around a single, encapsulated sulfate anion.
ISSN:1364-548X
DOI:10.1039/c2cc35095e