One-Pot Synthesis of Symmetrical and Unsymmetrical Diarylmethanes via Diborylmethane

A one-pot synthesis of diarylmethanes from air-stable diborylmethane via the Suzuki–Miyaura cross-coupling reaction is described. The present approach realizes the synthesis of various symmetrical and unsymmetrical diarylmethanes in good to excellent yields.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of organic chemistry 2012-09, Vol.77 (17), p.7223-7231
Hauptverfasser:	Endo, Kohei, Ishioka, Takafumi, Ohkubo, Takahiro, Shibata, Takanori
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzhydryl Compounds - chemical synthesis Benzhydryl Compounds - chemistry Boron Compounds - chemistry Chemistry Exact sciences and technology Heterocyclic compounds Methane - analogs & derivatives Methane - chemistry Miscellaneous Molecular Structure Noncondensed benzenic compounds Organic chemistry Preparations and properties Stereoisomerism
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Beschreibung
Zusammenfassung:	A one-pot synthesis of diarylmethanes from air-stable diborylmethane via the Suzuki–Miyaura cross-coupling reaction is described. The present approach realizes the synthesis of various symmetrical and unsymmetrical diarylmethanes in good to excellent yields.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo3015165