Blue shift in the optical band gap of amorphous HfaInaZnaO thin films deposited by RF sputtering

Amorphous HfaInaZnaO (a-HIZO) thin films were grown by radio frequency (RF) magnetron sputtering in a mixed atmosphere of Ar and O2 at fixed 5 mTorr working pressure. A 13% enhancement (blue shift) in band gap from 3.59 eV to 4.06 eV was obtained as O2/Ar flow ratio increased from 5% to 50%. a-HIZO...

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Veröffentlicht in:Journal of alloys and compounds 2012-06, Vol.525, p.172-174
Hauptverfasser: Thakur, Anup, Kang, Se-Jun, Baik, Jae Yoon, Yoo, Hanbyeol, Lee, Ik-Jae, Lee, Han-Koo, Jung, Seonghoon, Park, Jaehun, Shin, Hyun-Joon
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container_end_page 174
container_issue
container_start_page 172
container_title Journal of alloys and compounds
container_volume 525
creator Thakur, Anup
Kang, Se-Jun
Baik, Jae Yoon
Yoo, Hanbyeol
Lee, Ik-Jae
Lee, Han-Koo
Jung, Seonghoon
Park, Jaehun
Shin, Hyun-Joon
description Amorphous HfaInaZnaO (a-HIZO) thin films were grown by radio frequency (RF) magnetron sputtering in a mixed atmosphere of Ar and O2 at fixed 5 mTorr working pressure. A 13% enhancement (blue shift) in band gap from 3.59 eV to 4.06 eV was obtained as O2/Ar flow ratio increased from 5% to 50%. a-HIZO films deposited at higher O2/Ar gas flow ratio were more resistive. Oxygen-incorporation-induced reduction of oxygen vacancies is suggested to explain the band gap and resistivity increase.
doi_str_mv 10.1016/j.jallcom.2012.02.091
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subjects Alloys
Barometric pressure
Blue shift
Deposition
Electrical resistivity
Radio frequencies
Thin films
Vacancies
title Blue shift in the optical band gap of amorphous HfaInaZnaO thin films deposited by RF sputtering
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