Efficient Resolution of Some Monoprotected Derivatives of Corey Lactone

Efficient Resolution of Some Monoprotected Derivatives of Corey Lactone

Racemic monoprotected at primary hydroxy group Corey lactones were resolved using (1S,2R,5R)-6,6-dimethyl-4-oxo-3-oxabicyclo-[3.1.0]hexan-2-ol as a chiral auxiliary reagent of hemiacylal chemotype.

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Veröffentlicht in:Mendeleev communications 2012-05, Vol.22 (3), p.125-126
Hauptverfasser: Loza, Vladimir V., Vostrikov, Nikolay S., Miftakhov, Mansur S.
Format: Artikel
Sprache:eng
Schlagworte:
Derivatives
Lactones
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Zusammenfassung:Racemic monoprotected at primary hydroxy group Corey lactones were resolved using (1S,2R,5R)-6,6-dimethyl-4-oxo-3-oxabicyclo-[3.1.0]hexan-2-ol as a chiral auxiliary reagent of hemiacylal chemotype.
ISSN:0959-9436
DOI:10.1016/j.mencom.2012.05.002