Highly dispersive {001} facets-exposed nanocrystalline TiO sub(2) on high quality graphene as a high performance photocatalyst

A series of composites of nanocrystalline TiO sub(2) with exposed {001} facets and high quality graphene sheets (GS) were synthesized viaa one-step hydrothermal reaction in an ethanol-water solvent. The obtained {001} facets-exposed TiO sub(2)/GS photocatalysts were characterized by Raman spectroscopy (RS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction pattern (XRD), field emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet visible (UV-vis) diffuse reflectance spectroscopy (DRS) and Electrical Impedance Spectroscopy (EIS). They showed a better photocatalyst properties than P25 and other normal TiO sub(2)/GS composites, which could be explained on the basis of the formation of chemical Ti-O-C bond and the formation of nano-sized Schottky interfaces at the contacts between TiO sub(2) and GS. The influence of the exposed {001} facets on the photocatalytic activity was investigated. The result showed that positively charged dye molecules are preferentially adsorbed onto the TiO sub(2)/GS composites due to the photogenerated charge gathered on GS. Overall, this work could provide new insights into the fabrication of TiO sub(2)-carbon composites as high performance photocatalysts and facilitate their application in addressing environmental protection issues.