A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers
A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the...
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Veröffentlicht in: | International journal of thermal sciences 2012-08, Vol.58, p.102-112 |
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description | A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the Avrami–Kolmogorov kinetics with a modification for the flow-induced crystallization, and uses a Newtonian rheology where the dynamic viscosity is a function of the temperature, molecular orientation and degree of crystallization. The model is based on the leading-order one-dimensional equations for the fiber's geometry and axial and radial velocity components determined from an asymptotic analysis of slender fibers at low Reynolds numbers, and two-dimensional equations for the temperature, molecular orientation tensor and crystallization. It is shown that almost complete molecular orientation is achieved close to the maximum swell cross-section due to the large contraction of the fiber there, whereas, for the conditions considered here, the ultimate degree of crystallization is not achieved at the take-up cross-section. It is also shown that there are non-uniformities in the temperature and crystallinity profiles at the take-up cross-section which may have an effect on the fiber's properties.
► A two-dimensional model of semicrystalline hollow compound fibers is proposed. ► Full molecular orientation is achieved near the maximum swell cross-section. ► The ultimate degree of crystallization is not achieved. ► The degree of crystallization is not homogeneous in the radial direction. |
doi_str_mv | 10.1016/j.ijthermalsci.2012.03.008 |
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► A two-dimensional model of semicrystalline hollow compound fibers is proposed. ► Full molecular orientation is achieved near the maximum swell cross-section. ► The ultimate degree of crystallization is not achieved. ► The degree of crystallization is not homogeneous in the radial direction.</description><identifier>ISSN: 1290-0729</identifier><identifier>EISSN: 1778-4166</identifier><identifier>DOI: 10.1016/j.ijthermalsci.2012.03.008</identifier><language>eng</language><publisher>Kidlington: Elsevier Masson SAS</publisher><subject>Applied sciences ; Avrami–Kolmogorov model ; Cross sections ; Crystallization ; Doi–Edwards theory ; Exact sciences and technology ; Fibers ; Hollow compound fibers ; Machinery and processing ; Mathematical analysis ; Mathematical models ; Melt spinning ; Molecular orientation tensor ; Newtonian rheology ; Orientation ; Plastics ; Polymer industry, paints, wood ; Spinning ; Technology of polymers ; Two dimensional</subject><ispartof>International journal of thermal sciences, 2012-08, Vol.58, p.102-112</ispartof><rights>2012 Elsevier Masson SAS</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c387t-fc6889348e12e024fda92bcac462697a35a396b783eeb72a5c7bda7199ff01b53</citedby><cites>FETCH-LOGICAL-c387t-fc6889348e12e024fda92bcac462697a35a396b783eeb72a5c7bda7199ff01b53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1290072912000981$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25955216$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Blanco-Rodríguez, Francisco J.</creatorcontrib><creatorcontrib>Ramos, J.I.</creatorcontrib><title>A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers</title><title>International journal of thermal sciences</title><description>A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the Avrami–Kolmogorov kinetics with a modification for the flow-induced crystallization, and uses a Newtonian rheology where the dynamic viscosity is a function of the temperature, molecular orientation and degree of crystallization. The model is based on the leading-order one-dimensional equations for the fiber's geometry and axial and radial velocity components determined from an asymptotic analysis of slender fibers at low Reynolds numbers, and two-dimensional equations for the temperature, molecular orientation tensor and crystallization. It is shown that almost complete molecular orientation is achieved close to the maximum swell cross-section due to the large contraction of the fiber there, whereas, for the conditions considered here, the ultimate degree of crystallization is not achieved at the take-up cross-section. It is also shown that there are non-uniformities in the temperature and crystallinity profiles at the take-up cross-section which may have an effect on the fiber's properties.
► A two-dimensional model of semicrystalline hollow compound fibers is proposed. ► Full molecular orientation is achieved near the maximum swell cross-section. ► The ultimate degree of crystallization is not achieved. ► The degree of crystallization is not homogeneous in the radial direction.</description><subject>Applied sciences</subject><subject>Avrami–Kolmogorov model</subject><subject>Cross sections</subject><subject>Crystallization</subject><subject>Doi–Edwards theory</subject><subject>Exact sciences and technology</subject><subject>Fibers</subject><subject>Hollow compound fibers</subject><subject>Machinery and processing</subject><subject>Mathematical analysis</subject><subject>Mathematical models</subject><subject>Melt spinning</subject><subject>Molecular orientation tensor</subject><subject>Newtonian rheology</subject><subject>Orientation</subject><subject>Plastics</subject><subject>Polymer industry, paints, wood</subject><subject>Spinning</subject><subject>Technology of polymers</subject><subject>Two dimensional</subject><issn>1290-0729</issn><issn>1778-4166</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqNkEuLFTEQhRtRcBz9D0EQ3HRPHt2dxN0wPkYYcKPrkE5XnLrk0SZ9Hebfm8sdxKWrKoqvzqk6XfeW0YFRNl8dBjzs91CiDdXhwCnjAxUDpepZd8GkVP3I5vl567mmPZVcv-xe1XqglEpN9UW3XJOKcQvoEVayP-R-xQipYk42kJhXCCR70jxIhLCTumFKmH6ehhUi9q481t2GgAnIfQ4hPxCX45aPaSUeFyj1dffCt_PgzVO97H58_vT95ra_-_bl6831Xe-Eknvv3ayUFqMCxoHy0a9W88VZN8581tKKyQo9L1IJgEVyOzm5rFYyrb2nbJnEZff-rLuV_OsIdTcRq4MQbIJ8rIZRofioKKcN_XBGXcm1FvBmKxhteWyQOQVrDubfYM0pWEOFacG25XdPPrY6G3yxyWH9q8AnPU2czY37eOagPf0boZimBMnBigXcbtaM_2P3BypTl1o</recordid><startdate>20120801</startdate><enddate>20120801</enddate><creator>Blanco-Rodríguez, Francisco J.</creator><creator>Ramos, J.I.</creator><general>Elsevier Masson SAS</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20120801</creationdate><title>A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers</title><author>Blanco-Rodríguez, Francisco J. ; Ramos, J.I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c387t-fc6889348e12e024fda92bcac462697a35a396b783eeb72a5c7bda7199ff01b53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Avrami–Kolmogorov model</topic><topic>Cross sections</topic><topic>Crystallization</topic><topic>Doi–Edwards theory</topic><topic>Exact sciences and technology</topic><topic>Fibers</topic><topic>Hollow compound fibers</topic><topic>Machinery and processing</topic><topic>Mathematical analysis</topic><topic>Mathematical models</topic><topic>Melt spinning</topic><topic>Molecular orientation tensor</topic><topic>Newtonian rheology</topic><topic>Orientation</topic><topic>Plastics</topic><topic>Polymer industry, paints, wood</topic><topic>Spinning</topic><topic>Technology of polymers</topic><topic>Two dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Blanco-Rodríguez, Francisco J.</creatorcontrib><creatorcontrib>Ramos, J.I.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>International journal of thermal sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Blanco-Rodríguez, Francisco J.</au><au>Ramos, J.I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers</atitle><jtitle>International journal of thermal sciences</jtitle><date>2012-08-01</date><risdate>2012</risdate><volume>58</volume><spage>102</spage><epage>112</epage><pages>102-112</pages><issn>1290-0729</issn><eissn>1778-4166</eissn><abstract>A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the Avrami–Kolmogorov kinetics with a modification for the flow-induced crystallization, and uses a Newtonian rheology where the dynamic viscosity is a function of the temperature, molecular orientation and degree of crystallization. The model is based on the leading-order one-dimensional equations for the fiber's geometry and axial and radial velocity components determined from an asymptotic analysis of slender fibers at low Reynolds numbers, and two-dimensional equations for the temperature, molecular orientation tensor and crystallization. It is shown that almost complete molecular orientation is achieved close to the maximum swell cross-section due to the large contraction of the fiber there, whereas, for the conditions considered here, the ultimate degree of crystallization is not achieved at the take-up cross-section. It is also shown that there are non-uniformities in the temperature and crystallinity profiles at the take-up cross-section which may have an effect on the fiber's properties.
► A two-dimensional model of semicrystalline hollow compound fibers is proposed. ► Full molecular orientation is achieved near the maximum swell cross-section. ► The ultimate degree of crystallization is not achieved. ► The degree of crystallization is not homogeneous in the radial direction.</abstract><cop>Kidlington</cop><pub>Elsevier Masson SAS</pub><doi>10.1016/j.ijthermalsci.2012.03.008</doi><tpages>11</tpages></addata></record> |
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subjects | Applied sciences Avrami–Kolmogorov model Cross sections Crystallization Doi–Edwards theory Exact sciences and technology Fibers Hollow compound fibers Machinery and processing Mathematical analysis Mathematical models Melt spinning Molecular orientation tensor Newtonian rheology Orientation Plastics Polymer industry, paints, wood Spinning Technology of polymers Two dimensional |
title | A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers |
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