A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers

A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the...

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Veröffentlicht in:International journal of thermal sciences 2012-08, Vol.58, p.102-112
Hauptverfasser: Blanco-Rodríguez, Francisco J., Ramos, J.I.
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Ramos, J.I.
description A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the Avrami–Kolmogorov kinetics with a modification for the flow-induced crystallization, and uses a Newtonian rheology where the dynamic viscosity is a function of the temperature, molecular orientation and degree of crystallization. The model is based on the leading-order one-dimensional equations for the fiber's geometry and axial and radial velocity components determined from an asymptotic analysis of slender fibers at low Reynolds numbers, and two-dimensional equations for the temperature, molecular orientation tensor and crystallization. It is shown that almost complete molecular orientation is achieved close to the maximum swell cross-section due to the large contraction of the fiber there, whereas, for the conditions considered here, the ultimate degree of crystallization is not achieved at the take-up cross-section. It is also shown that there are non-uniformities in the temperature and crystallinity profiles at the take-up cross-section which may have an effect on the fiber's properties. ► A two-dimensional model of semicrystalline hollow compound fibers is proposed. ► Full molecular orientation is achieved near the maximum swell cross-section. ► The ultimate degree of crystallization is not achieved. ► The degree of crystallization is not homogeneous in the radial direction.
doi_str_mv 10.1016/j.ijthermalsci.2012.03.008
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ispartof International journal of thermal sciences, 2012-08, Vol.58, p.102-112
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1778-4166
language eng
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source Elsevier ScienceDirect Journals
subjects Applied sciences
Avrami–Kolmogorov model
Cross sections
Crystallization
Doi–Edwards theory
Exact sciences and technology
Fibers
Hollow compound fibers
Machinery and processing
Mathematical analysis
Mathematical models
Melt spinning
Molecular orientation tensor
Newtonian rheology
Orientation
Plastics
Polymer industry, paints, wood
Spinning
Technology of polymers
Two dimensional
title A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers
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