A simplified two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers
A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the...
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Veröffentlicht in: | International journal of thermal sciences 2012-08, Vol.58, p.102-112 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A two-dimensional model of the melt spinning of semi-crystalline hollow compound fibers is presented. The model accounts for the orientation of the polymer molecules by means of a Doi–Edwards formulation for the molecular orientation tensor, and for the crystallization of the polymer by means of the Avrami–Kolmogorov kinetics with a modification for the flow-induced crystallization, and uses a Newtonian rheology where the dynamic viscosity is a function of the temperature, molecular orientation and degree of crystallization. The model is based on the leading-order one-dimensional equations for the fiber's geometry and axial and radial velocity components determined from an asymptotic analysis of slender fibers at low Reynolds numbers, and two-dimensional equations for the temperature, molecular orientation tensor and crystallization. It is shown that almost complete molecular orientation is achieved close to the maximum swell cross-section due to the large contraction of the fiber there, whereas, for the conditions considered here, the ultimate degree of crystallization is not achieved at the take-up cross-section. It is also shown that there are non-uniformities in the temperature and crystallinity profiles at the take-up cross-section which may have an effect on the fiber's properties.
► A two-dimensional model of semicrystalline hollow compound fibers is proposed. ► Full molecular orientation is achieved near the maximum swell cross-section. ► The ultimate degree of crystallization is not achieved. ► The degree of crystallization is not homogeneous in the radial direction. |
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ISSN: | 1290-0729 1778-4166 |
DOI: | 10.1016/j.ijthermalsci.2012.03.008 |