Study on the influence of channel structure properties in the dehydration of glycerol to acrolein over H-zeolite catalysts

[Display omitted] ► H-zeolites with smaller channels favored glycerol dehydration to acrolein. ► HZSM-11 exhibited superior catalytic performance than HZSM-5. ► The introduction of carrier gas could improve catalytic performance of H-zeolites. ► Coke was initially deposited at channel intersections of H-zeolites. ► External surface of H-zeolites supplied room for coke deposition during reaction. Systematic studies have been conducted over several selected H-zeolites, namely HZSM-5, H-Beta, HY, nano HZSM-5, HZSM-11 and nano HZSM-11, aimed to investigate influence of the channel structure on catalytic performance for gas phase dehydration of glycerol to acrolein. Compared to H-Beta and HY, improved catalytic performance was discovered over HZSM-5, which demonstrated that H-zeolites with smaller channels, the ones marginally larger than the molecular diameter of glycerol, were preferential for the reaction. HZSM-11, with lower channel complexity, was more likely to obtain superior catalytic performance due to enhanced diffusion. Nano HZSM-11 (300–500nm) exhibited excellent catalytic performance with 81.6mol% glycerol conversion and 74.9mol% acrolein selectivity at GHSV as high as 873h−1 (TOS=8h). BET and TEM experiment results indicated that coke was initially deposited at channel intersections of H-zeolites, and when the channel blockage came up to a certain extent, there arrived the onset of coke deposition on the external surface.