Chiral assembly of dodecahedral cavities into porous metal-organic frameworks

Chiral assembly of dodecahedral cavities into porous metal-organic frameworks

Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M(2)(CO(2))(4)] units and trimeric [M(3)(μ(3)-OH)(CO(2))(6)] units leads to two isomorphous chiral microporous metal-organic frameworks, where the heterometallic framework has high surface area and excellent CO(2)/N(2) adsorpti...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-09, Vol.48 (75), p.9424-9426
Hauptverfasser: Yang, Hui, Wang, Fei, Kang, Yao, Li, Tie-Hu, Zhang, Jian
Format: Artikel
Sprache:eng
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Zusammenfassung:Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M(2)(CO(2))(4)] units and trimeric [M(3)(μ(3)-OH)(CO(2))(6)] units leads to two isomorphous chiral microporous metal-organic frameworks, where the heterometallic framework has high surface area and excellent CO(2)/N(2) adsorption selectivity.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc35024f