Oxidative kinetic resolution of racemic secondary alcohols in water with chiral PNNP/Ir catalyst

Using water as solvent, the oxidative kinetic resolution of a wide range of racemic secondary alcohols with a chiral PNNP/Ir catalyst was investigated. The catalytic reaction proceeded smoothly with excellent enantioselectivity (up to 97% ee) under mild conditions, providing an environmentally benig...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2012-01, Vol.14 (5), p.1289-1292
Hauptverfasser:	Zhang, Juanni, Yang, Xiangren, Zhou, Han, Li, Yanyun, Dong, Zhenrong, Gao, Jingxing
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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creator	Zhang, Juanni Yang, Xiangren Zhou, Han Li, Yanyun Dong, Zhenrong Gao, Jingxing
description	Using water as solvent, the oxidative kinetic resolution of a wide range of racemic secondary alcohols with a chiral PNNP/Ir catalyst was investigated. The catalytic reaction proceeded smoothly with excellent enantioselectivity (up to 97% ee) under mild conditions, providing an environmentally benign process to achieve optically active alcohols.
doi_str_mv	10.1039/c2gc00028h
format	Article
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title	Oxidative kinetic resolution of racemic secondary alcohols in water with chiral PNNP/Ir catalyst
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