Oxidative kinetic resolution of racemic secondary alcohols in water with chiral PNNP/Ir catalyst

Using water as solvent, the oxidative kinetic resolution of a wide range of racemic secondary alcohols with a chiral PNNP/Ir catalyst was investigated. The catalytic reaction proceeded smoothly with excellent enantioselectivity (up to 97% ee) under mild conditions, providing an environmentally benig...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2012-01, Vol.14 (5), p.1289-1292
Hauptverfasser:	Zhang, Juanni, Yang, Xiangren, Zhou, Han, Li, Yanyun, Dong, Zhenrong, Gao, Jingxing
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Using water as solvent, the oxidative kinetic resolution of a wide range of racemic secondary alcohols with a chiral PNNP/Ir catalyst was investigated. The catalytic reaction proceeded smoothly with excellent enantioselectivity (up to 97% ee) under mild conditions, providing an environmentally benign process to achieve optically active alcohols.
ISSN:	1463-9262 1463-9270
DOI:	10.1039/c2gc00028h