Graphene from Sugar and its Application in Water Purification
This paper describes a green method for the synthesis of graphenic material from cane sugar, a common disaccharide. A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman...
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Veröffentlicht in: | ACS applied materials & interfaces 2012-08, Vol.4 (8), p.4156-4163 |
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description | This paper describes a green method for the synthesis of graphenic material from cane sugar, a common disaccharide. A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman spectroscopy confirmed that the material is indeed graphenic in nature, having G and D bands at 1597 and 1338 cm–1, respectively. It effectively removes contaminants from water. Here, we use rhodamine 6G (R6G) as a model dye and chloropyrifos (CP) as a model pesticide to demonstrate this application. The spectroscopic and microscopic analyses coupled with adsorption experiments revealed that physical adsorption plays a dominant role in the adsorption process. Isotherm data in batch experiments show an adsorption capacity of 55 mg/g for R6G and 48 mg/g for CP, which are superior to that of activated carbon. The adsorbent can be easily regenerated using a suitable eluent. This quick and cost-effective technique for the into a commercial water filter with appropriate engineering. |
doi_str_mv | 10.1021/am300889u |
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A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman spectroscopy confirmed that the material is indeed graphenic in nature, having G and D bands at 1597 and 1338 cm–1, respectively. It effectively removes contaminants from water. Here, we use rhodamine 6G (R6G) as a model dye and chloropyrifos (CP) as a model pesticide to demonstrate this application. The spectroscopic and microscopic analyses coupled with adsorption experiments revealed that physical adsorption plays a dominant role in the adsorption process. Isotherm data in batch experiments show an adsorption capacity of 55 mg/g for R6G and 48 mg/g for CP, which are superior to that of activated carbon. The adsorbent can be easily regenerated using a suitable eluent. This quick and cost-effective technique for the into a commercial water filter with appropriate engineering.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/am300889u</identifier><identifier>PMID: 22788773</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Adsorption ; Carbohydrates - chemistry ; Coloring Agents - chemistry ; Disaccharides - chemistry ; Graphite - chemistry ; Kinetics ; Mass Spectrometry - methods ; Microscopy, Electron, Scanning - methods ; Models, Chemical ; Pesticides - chemistry ; Rhodamines - chemistry ; Spectrophotometry, Ultraviolet - methods ; Spectrum Analysis, Raman - methods ; Sulfuric Acids - chemistry ; Time Factors ; Water - chemistry ; Water Pollutants, Chemical - chemistry ; Water Purification - methods</subject><ispartof>ACS applied materials & interfaces, 2012-08, Vol.4 (8), p.4156-4163</ispartof><rights>Copyright © 2012 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-f289da063c386a3e481b33b6779b29833788d1faa07c07191bedae17160f713</citedby><cites>FETCH-LOGICAL-a381t-f289da063c386a3e481b33b6779b29833788d1faa07c07191bedae17160f713</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/am300889u$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/am300889u$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22788773$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gupta, Soujit Sen</creatorcontrib><creatorcontrib>Sreeprasad, Theruvakkattil Sreenivasan</creatorcontrib><creatorcontrib>Maliyekkal, Shihabudheen Mundampra</creatorcontrib><creatorcontrib>Das, Sarit Kumar</creatorcontrib><creatorcontrib>Pradeep, Thalappil</creatorcontrib><title>Graphene from Sugar and its Application in Water Purification</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl. Mater. Interfaces</addtitle><description>This paper describes a green method for the synthesis of graphenic material from cane sugar, a common disaccharide. A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman spectroscopy confirmed that the material is indeed graphenic in nature, having G and D bands at 1597 and 1338 cm–1, respectively. It effectively removes contaminants from water. Here, we use rhodamine 6G (R6G) as a model dye and chloropyrifos (CP) as a model pesticide to demonstrate this application. The spectroscopic and microscopic analyses coupled with adsorption experiments revealed that physical adsorption plays a dominant role in the adsorption process. Isotherm data in batch experiments show an adsorption capacity of 55 mg/g for R6G and 48 mg/g for CP, which are superior to that of activated carbon. The adsorbent can be easily regenerated using a suitable eluent. This quick and cost-effective technique for the into a commercial water filter with appropriate engineering.</description><subject>Adsorption</subject><subject>Carbohydrates - chemistry</subject><subject>Coloring Agents - chemistry</subject><subject>Disaccharides - chemistry</subject><subject>Graphite - chemistry</subject><subject>Kinetics</subject><subject>Mass Spectrometry - methods</subject><subject>Microscopy, Electron, Scanning - methods</subject><subject>Models, Chemical</subject><subject>Pesticides - chemistry</subject><subject>Rhodamines - chemistry</subject><subject>Spectrophotometry, Ultraviolet - methods</subject><subject>Spectrum Analysis, Raman - methods</subject><subject>Sulfuric Acids - chemistry</subject><subject>Time Factors</subject><subject>Water - chemistry</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Purification - methods</subject><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkE1LAzEQhoMotlYP_gHJRdDDar66yR48lKJVKChU8LjM7iaasl8mm4P_vpGtPXmaYXh4Z-ZB6JKSO0oYvYeGE6JUFo7QlGZCJIrN2fGhF2KCzrzfEpJyRuanaMKYVEpKPkUPKwf9l241Nq5r8CZ8gsPQVtgOHi_6vrYlDLZrsW3xBwza4bfgrNlPz9GJgdrri32doc3T4_vyOVm_rl6Wi3UCXNEhMUxlFcTtJVcpcC0ULTgvUimzgmWK83hNRQ0AkSWRNKOFrkBTSVNiJOUzdDOm9q77DtoPeWN9qesaWt0Fn1PChSJKCB7R2xEtXee90ybvnW3A_UQo_3WVH1xF9mofG4pGVwfyT04ErkcASp9vu-Da-OM_QTv5nG6Q</recordid><startdate>20120822</startdate><enddate>20120822</enddate><creator>Gupta, Soujit Sen</creator><creator>Sreeprasad, Theruvakkattil Sreenivasan</creator><creator>Maliyekkal, Shihabudheen Mundampra</creator><creator>Das, Sarit Kumar</creator><creator>Pradeep, Thalappil</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20120822</creationdate><title>Graphene from Sugar and its Application in Water Purification</title><author>Gupta, Soujit Sen ; Sreeprasad, Theruvakkattil Sreenivasan ; Maliyekkal, Shihabudheen Mundampra ; Das, Sarit Kumar ; Pradeep, Thalappil</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-f289da063c386a3e481b33b6779b29833788d1faa07c07191bedae17160f713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Adsorption</topic><topic>Carbohydrates - chemistry</topic><topic>Coloring Agents - chemistry</topic><topic>Disaccharides - chemistry</topic><topic>Graphite - chemistry</topic><topic>Kinetics</topic><topic>Mass Spectrometry - methods</topic><topic>Microscopy, Electron, Scanning - methods</topic><topic>Models, Chemical</topic><topic>Pesticides - chemistry</topic><topic>Rhodamines - chemistry</topic><topic>Spectrophotometry, Ultraviolet - methods</topic><topic>Spectrum Analysis, Raman - methods</topic><topic>Sulfuric Acids - chemistry</topic><topic>Time Factors</topic><topic>Water - chemistry</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water Purification - methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gupta, Soujit Sen</creatorcontrib><creatorcontrib>Sreeprasad, Theruvakkattil Sreenivasan</creatorcontrib><creatorcontrib>Maliyekkal, Shihabudheen Mundampra</creatorcontrib><creatorcontrib>Das, Sarit Kumar</creatorcontrib><creatorcontrib>Pradeep, Thalappil</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gupta, Soujit Sen</au><au>Sreeprasad, Theruvakkattil Sreenivasan</au><au>Maliyekkal, Shihabudheen Mundampra</au><au>Das, Sarit Kumar</au><au>Pradeep, Thalappil</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graphene from Sugar and its Application in Water Purification</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2012-08-22</date><risdate>2012</risdate><volume>4</volume><issue>8</issue><spage>4156</spage><epage>4163</epage><pages>4156-4163</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>This paper describes a green method for the synthesis of graphenic material from cane sugar, a common disaccharide. A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman spectroscopy confirmed that the material is indeed graphenic in nature, having G and D bands at 1597 and 1338 cm–1, respectively. It effectively removes contaminants from water. Here, we use rhodamine 6G (R6G) as a model dye and chloropyrifos (CP) as a model pesticide to demonstrate this application. The spectroscopic and microscopic analyses coupled with adsorption experiments revealed that physical adsorption plays a dominant role in the adsorption process. Isotherm data in batch experiments show an adsorption capacity of 55 mg/g for R6G and 48 mg/g for CP, which are superior to that of activated carbon. The adsorbent can be easily regenerated using a suitable eluent. This quick and cost-effective technique for the into a commercial water filter with appropriate engineering.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>22788773</pmid><doi>10.1021/am300889u</doi><tpages>8</tpages></addata></record> |
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subjects | Adsorption Carbohydrates - chemistry Coloring Agents - chemistry Disaccharides - chemistry Graphite - chemistry Kinetics Mass Spectrometry - methods Microscopy, Electron, Scanning - methods Models, Chemical Pesticides - chemistry Rhodamines - chemistry Spectrophotometry, Ultraviolet - methods Spectrum Analysis, Raman - methods Sulfuric Acids - chemistry Time Factors Water - chemistry Water Pollutants, Chemical - chemistry Water Purification - methods |
title | Graphene from Sugar and its Application in Water Purification |
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