Graphene from Sugar and its Application in Water Purification

This paper describes a green method for the synthesis of graphenic material from cane sugar, a common disaccharide. A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman...

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Veröffentlicht in:ACS applied materials & interfaces 2012-08, Vol.4 (8), p.4156-4163
Hauptverfasser: Gupta, Soujit Sen, Sreeprasad, Theruvakkattil Sreenivasan, Maliyekkal, Shihabudheen Mundampra, Das, Sarit Kumar, Pradeep, Thalappil
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Sprache:eng
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Zusammenfassung:This paper describes a green method for the synthesis of graphenic material from cane sugar, a common disaccharide. A suitable methodology was introduced to immobilize this material on sand without the need of any binder, resulting in a composite, referred to as graphene sand composite (GSC). Raman spectroscopy confirmed that the material is indeed graphenic in nature, having G and D bands at 1597 and 1338 cm–1, respectively. It effectively removes contaminants from water. Here, we use rhodamine 6G (R6G) as a model dye and chloropyrifos (CP) as a model pesticide to demonstrate this application. The spectroscopic and microscopic analyses coupled with adsorption experiments revealed that physical adsorption plays a dominant role in the adsorption process. Isotherm data in batch experiments show an adsorption capacity of 55 mg/g for R6G and 48 mg/g for CP, which are superior to that of activated carbon. The adsorbent can be easily regenerated using a suitable eluent. This quick and cost-effective technique for the into a commercial water filter with appropriate engineering.
ISSN:1944-8244
1944-8252
DOI:10.1021/am300889u