Rhodium(III)- and Ruthenium(II)-Catalyzed Olefination of Isoquinolones

NH and N-protected isoquinolones undergo Rh(III)-catalyzed oxidative olefination at the 8-position. Complementary redox-neutral olefination of such isoquinolones using internal alkynes was achieved under ruthenium catalysis.

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Veröffentlicht in:	Organic letters 2012-08, Vol.14 (16), p.4166-4169
Hauptverfasser:	Zhao, Peng, Niu, Rui, Wang, Fen, Han, Keli, Li, Xingwei
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Sprache:	eng
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creator	Zhao, Peng Niu, Rui Wang, Fen Han, Keli Li, Xingwei
description	NH and N-protected isoquinolones undergo Rh(III)-catalyzed oxidative olefination at the 8-position. Complementary redox-neutral olefination of such isoquinolones using internal alkynes was achieved under ruthenium catalysis.
doi_str_mv	10.1021/ol3018352
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title	Rhodium(III)- and Ruthenium(II)-Catalyzed Olefination of Isoquinolones
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