Catalytic Carbon–Carbon σ-Bond Hydrogenation with Water Catalyzed by Rhodium Porphyrins

Catalytic Carbon–Carbon σ-Bond Hydrogenation with Water Catalyzed by Rhodium Porphyrins

The catalytic carbon–carbon σ-bond activation and hydrogenation of [2.2]­paracyclophane with water in a neutral reaction medium is demonstrated. The hydrogen from water is transferred to the hydrocarbon to furnish hydrogen enrichment in good yields.

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Veröffentlicht in:Journal of the American Chemical Society 2012-07, Vol.134 (28), p.11388-11391
Hauptverfasser: To, Ching Tat, Choi, Kwong Shing, Chan, Kin Shing
Format: Artikel
Sprache:eng
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Zusammenfassung:The catalytic carbon–carbon σ-bond activation and hydrogenation of [2.2]­paracyclophane with water in a neutral reaction medium is demonstrated. The hydrogen from water is transferred to the hydrocarbon to furnish hydrogen enrichment in good yields.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja3047415