[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F···H···F– Bridges in a One-Dimensional Polymeric Chain

[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F···H···F– Bridges in a One-Dimensional Polymeric Chain

[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN4F2 octahedra that form chains with bridging HF2 – ligands. In spite of significant distortion of the HF2 – bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J FH...

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Veröffentlicht in:Inorganic chemistry 2012-07, Vol.51 (14), p.7520-7528
Hauptverfasser: Manson, Jamie L, Baldwin, Adora G, Scott, Brian L, Bendix, Jesper, Del Sesto, Rico E, Goddard, Paul A, Kohama, Yoshimitsu, Tran, Hope E, Ghannadzadeh, Saman, Singleton, John, Lancaster, Tom, Möller, Johannes S, Blundell, Stephen J, Pratt, Francis L, Zapf, Vivien S, Kang, Jinhee, Lee, Changhoon, Whangbo, Myung-Hwan, Baines, Christopher
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Sprache:eng
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Zusammenfassung:[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN4F2 octahedra that form chains with bridging HF2 – ligands. In spite of significant distortion of the HF2 – bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J FHF = 4.86 K.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic300111k