A [24-MC-6] Zinc Metallacoronate with a Nonsteroidal Antiinflammatory Drug as the Constructing Ligand

The interaction of ZnCl2 with 2-dipyridylketonoxime (=Hpko) and flufenamic acid (=Hfluf) in a basic methanolic solution leads to the formation of a hexanuclear 24-membered metallacoronate, [Zn6(OH)2(pko)4(fluf)6] (1), with a [Zn–O–C–O] repeat unit and a nonsteroidal antiinflammatory drug as the cons...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Inorganic chemistry 2012-07, Vol.51 (14), p.7460-7462
Hauptverfasser:	Tarushi, Alketa, Kastanias, Filippos, Psycharis, Vassilis, Raptopoulou, Catherine P, Psomas, George, Kessissoglou, Dimitris P
Format:	Artikel
Sprache:	eng
Schlagworte:	Anti-Inflammatory Agents, Non-Steroidal - chemical synthesis Anti-Inflammatory Agents, Non-Steroidal - chemistry Crystallography, X-Ray Flufenamic Acid - chemistry Ligands Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Zinc - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The interaction of ZnCl2 with 2-dipyridylketonoxime (=Hpko) and flufenamic acid (=Hfluf) in a basic methanolic solution leads to the formation of a hexanuclear 24-membered metallacoronate, [Zn6(OH)2(pko)4(fluf)6] (1), with a [Zn–O–C–O] repeat unit and a nonsteroidal antiinflammatory drug as the constructing ligand. Compound 1 retains its structure in a dimethyl sulfoxide solution, as shown by 1H NMR spectroscopy and molar conductance.
ISSN:	0020-1669 1520-510X
DOI:	10.1021/ic3010757