Ethylene Glycol: A Powerful Catalyst-Free Medium for CC Bond-Forming Reactions

Ethylene Glycol: A Powerful Catalyst-Free Medium for CC Bond-Forming Reactions

A good EG: Ethylene glycol (EG) is a catalyst‐free medium that can promote the highly efficient Strecker reaction of α‐CF2H or α‐CF3 ketoimines and TMSCN. EG was used in several reactions, including the catalyst‐free Morita–Baylis–Hillman reaction.

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Veröffentlicht in:Chemistry, an Asian journal an Asian journal, 2012-08, Vol.7 (8), p.1759-1763
Hauptverfasser: Liu, Yun-Lin, Zeng, Xing-Ping, Zhou, Jian
Format: Artikel
Sprache:eng
Schlagworte:
CC coupling
ethylene glycol
homogeneous reactions
solvent effects
Strecker reaction
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Zusammenfassung:A good EG: Ethylene glycol (EG) is a catalyst‐free medium that can promote the highly efficient Strecker reaction of α‐CF2H or α‐CF3 ketoimines and TMSCN. EG was used in several reactions, including the catalyst‐free Morita–Baylis–Hillman reaction.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201200289