Copper-catalyzed decarboxylative C(sp2)-C(sp3) coupling reactions via radical mechanism

Copper-catalyzed decarboxylative C(sp2)-C(sp3) coupling reactions via radical mechanism

We have successfully developed an example of copper-catalyzed decarboxylative C(sp(2))-C(sp(3)) coupling reactions via C-H functionalization for the first time. It is noteworthy that our catalytic system is very stable, low-cost, palladium-free, ligand-free, and easily accessible.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (63), p.7847-7849
Hauptverfasser: Yang, Hailong, Sun, Peng, Zhu, Yan, Yan, Hong, Lu, Linhua, Qu, Xiaoming, Li, Tingyi, Mao, Jincheng
Format: Artikel
Sprache:eng
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Zusammenfassung:We have successfully developed an example of copper-catalyzed decarboxylative C(sp(2))-C(sp(3)) coupling reactions via C-H functionalization for the first time. It is noteworthy that our catalytic system is very stable, low-cost, palladium-free, ligand-free, and easily accessible.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc33203e