Synthesis of Functionalized Acenaphthenes and a New Class of Homooxacalixarenes

Synthesis of Functionalized Acenaphthenes and a New Class of Homooxacalixarenes

The 5,6-dialkoxyethers of acenaphthene have been synthesized for the first time via modified Ullmann reaction conditions. Further modifications of the 5,6-dimethoxyacenaphthene allowed the synthesis of the first acenaphthene analogue of the octahomotetraoxacalixarenes. The X-ray structure of this ne...

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Veröffentlicht in:Organic letters 2012-07, Vol.14 (13), p.3530-3533
Hauptverfasser: AlHujran, Tayel A, Dawe, Louise N, Georghiou, Paris E
Format: Artikel
Sprache:eng
Schlagworte:
Acenaphthenes - chemical synthesis
Acenaphthenes - chemistry
Calixarenes - chemical synthesis
Calixarenes - chemistry
Crystallography, X-Ray
Models, Molecular
Molecular Structure
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Zusammenfassung:The 5,6-dialkoxyethers of acenaphthene have been synthesized for the first time via modified Ullmann reaction conditions. Further modifications of the 5,6-dimethoxyacenaphthene allowed the synthesis of the first acenaphthene analogue of the octahomotetraoxacalixarenes. The X-ray structure of this new macrocycle and its complexation study with C60 are reported.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol301538s