A Unified Approach to trans-Hydrindane Sesterterpenoids

A Unified Approach to trans-Hydrindane Sesterterpenoids

A synthetic approach to several sesterterpenoids containing an isopropyl trans-hydrindane system is presented. Its most remarkable feature is the stereochemical diversification of a common precursor through the choice of different hydrogenation conditions.

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Bibliographische Detailangaben
Veröffentlicht in:Journal of organic chemistry 2012-07, Vol.77 (13), p.5838-5843
Hauptverfasser: Hog, Daniel T, Mayer, Peter, Trauner, Dirk
Format: Artikel
Sprache:eng
Schlagworte:
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Crystallography, X-Ray
Exact sciences and technology
Hydrogenation
Indans - chemical synthesis
Indans - chemistry
Models, Molecular
Molecular Conformation
Organic chemistry
Preparations and properties
Sesterterpenes - chemical synthesis
Sesterterpenes - chemistry
Stereoisomerism
Terpenoids
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Beschreibung
Zusammenfassung:A synthetic approach to several sesterterpenoids containing an isopropyl trans-hydrindane system is presented. Its most remarkable feature is the stereochemical diversification of a common precursor through the choice of different hydrogenation conditions.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo300726z