Oxo/imido heterometathesis between N-sulfinylamines and ketones catalyzed by a silica-supported molybdenum imido complex

Oxo/imido heterometathesis between N-sulfinylamines and ketones catalyzed by a silica-supported molybdenum imido complex

Grafting the molecular complex (MesN)2Mo(CH2CMe2Ph)2 onto the surface of silica dramatically enhances its catalytic activity in the oxo/imido heterometathesis reaction of N-sulfinylamines with carbonyl compounds.

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Veröffentlicht in:Mendeleev communications 2012-03, Vol.22 (2), p.64-66
Hauptverfasser: Zhizhko, Pavel A., Zhizhin, Anton A., Zarubin, Dmitry N., Ustynyuk, Nikolai A.
Format: Artikel
Sprache:eng
Schlagworte:
Carbonyl compounds
Catalytic activity
Grafting
Ketones
Molybdenum
Silicon dioxide
Surface chemistry
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Beschreibung
Zusammenfassung:Grafting the molecular complex (MesN)2Mo(CH2CMe2Ph)2 onto the surface of silica dramatically enhances its catalytic activity in the oxo/imido heterometathesis reaction of N-sulfinylamines with carbonyl compounds.
ISSN:0959-9436
DOI:10.1016/j.mencom.2012.03.003