Lithiated Porous Aromatic Frameworks with Exceptional Gas Storage Capacity

Lithiated Porous Aromatic Frameworks with Exceptional Gas Storage Capacity

A porous treasure: Porous aromatic framework PAF‐1 (see picture, blue structure) has been lithiated, giving a reduced framework with an increased gas storage capacity compared to native PAF‐1 (by 22, 71, and 320 % for H2, CH4, and CO2, respectively). The reduced framework was examined spectroscopica...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-07, Vol.51 (27), p.6639-6642
Hauptverfasser: Konstas, Kristina, Taylor, James W., Thornton, Aaron W., Doherty, Cara M., Lim, Wei Xian, Bastow, Timothy J., Kennedy, Danielle F., Wood, Colin D., Cox, Barry J., Hill, James M., Hill, Anita J., Hill, Matthew R.
Format: Artikel
Sprache:eng
Schlagworte:
adsorption
gas storage
hydrogen
lithiation
porous aromatic frameworks
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Zusammenfassung:A porous treasure: Porous aromatic framework PAF‐1 (see picture, blue structure) has been lithiated, giving a reduced framework with an increased gas storage capacity compared to native PAF‐1 (by 22, 71, and 320 % for H2, CH4, and CO2, respectively). The reduced framework was examined spectroscopically, and the potential hydrogen storage capacity was calculated.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201201381