Watching Water Migration around a Peptide Bond

A long and winding road: The motion of a single water ligand around a peptide bond in acetanilide was probed in real time by time‐resolved IR spectroscopy. Triggered by photoionization, the H2O ligand is released from the CO site of the peptide linkage and trapped after a migration time of 5 ps at t...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2012-07, Vol.51 (27), p.6604-6607
Hauptverfasser:	Tanabe, Kohei, Miyazaki, Mitsuhiko, Schmies, Matthias, Patzer, Alexander, Schütz, Markus, Sekiya, Hiroshi, Sakai, Makoto, Dopfer, Otto, Fujii, Masaaki
Format:	Artikel
Sprache:	eng
Schlagworte:	hydration Hydrogen Bonding hydrogen bonds IR spectroscopy isomerization Models, Chemical peptides Peptides - chemistry Peptides - metabolism Permeability Spectrophotometry, Infrared Water - chemistry Water - metabolism
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!