A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere

An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (57), p.7203-7205
Hauptverfasser: Jiang, Hao, Lykke, Lennart, Pedersen, Steen Uttrup, Xiao, Wen-Jing, Jørgensen, Karl Anker
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container_end_page 7205
container_issue 57
container_start_page 7203
container_title Chemical communications (Cambridge, England)
container_volume 48
creator Jiang, Hao
Lykke, Lennart
Pedersen, Steen Uttrup
Xiao, Wen-Jing
Jørgensen, Karl Anker
description An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.
doi_str_mv 10.1039/c2cc32711b
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Alkanes - chemistry
Boronic Acids - chemistry
Electrolysis
Hydrocarbons, Aromatic - chemistry
Hydroxylation
Oxidation-Reduction
Superoxides - chemistry
title A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere
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