A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere
An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (57), p.7203-7205 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Jiang, Hao Lykke, Lennart Pedersen, Steen Uttrup Xiao, Wen-Jing Jørgensen, Karl Anker |
description | An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results. |
doi_str_mv | 10.1039/c2cc32711b |
format | Article |
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Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.</description><subject>Alkanes - chemistry</subject><subject>Boronic Acids - chemistry</subject><subject>Electrolysis</subject><subject>Hydrocarbons, Aromatic - chemistry</subject><subject>Hydroxylation</subject><subject>Oxidation-Reduction</subject><subject>Superoxides - chemistry</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpFkEtLxDAUhYMozji68QdIliJU82jaZjkMvmDAzSzclTS5ZaJpU5MWnH9vhhn1bs6B-3G49yB0Tck9JVw-aKY1ZyWlzQmaU17kmcir99O9FzIreS5m6CLGD5KGiuoczRgrJEvQHLVLPASlR6uVw-BAj8F3YKwawWA7RJ9tdyb4751To_U99i1WYeew6g1W7jO5xgffW42VtibiqTcQ0hYrm2TsfBy2EOASnbXKRbg66gJtnh43q5ds_fb8ulquM80FH7NSpcMgV5VUkhIpDSs5qUhTsFIIKQSTBSGVkSChKrVmiuY5pTovCLCGUr5At4fYIfivCeJYdzZqcE714KdYU8KorIjke_TugOrgYwzQ1kOwXfotQfW-1vq_1gTfHHOnJrXzh_72yH8Ae1xyvQ</recordid><startdate>20120101</startdate><enddate>20120101</enddate><creator>Jiang, Hao</creator><creator>Lykke, Lennart</creator><creator>Pedersen, Steen Uttrup</creator><creator>Xiao, Wen-Jing</creator><creator>Jørgensen, Karl Anker</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20120101</creationdate><title>A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere</title><author>Jiang, Hao ; Lykke, Lennart ; Pedersen, Steen Uttrup ; Xiao, Wen-Jing ; Jørgensen, Karl Anker</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-7a269e4a89a91099d273080b62755955296008d9e9e87cc2a14411c460e2b113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Alkanes - chemistry</topic><topic>Boronic Acids - chemistry</topic><topic>Electrolysis</topic><topic>Hydrocarbons, Aromatic - chemistry</topic><topic>Hydroxylation</topic><topic>Oxidation-Reduction</topic><topic>Superoxides - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiang, Hao</creatorcontrib><creatorcontrib>Lykke, Lennart</creatorcontrib><creatorcontrib>Pedersen, Steen Uttrup</creatorcontrib><creatorcontrib>Xiao, Wen-Jing</creatorcontrib><creatorcontrib>Jørgensen, Karl Anker</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiang, Hao</au><au>Lykke, Lennart</au><au>Pedersen, Steen Uttrup</au><au>Xiao, Wen-Jing</au><au>Jørgensen, Karl Anker</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2012-01-01</date><risdate>2012</risdate><volume>48</volume><issue>57</issue><spage>7203</spage><epage>7205</epage><pages>7203-7205</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. 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source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Alkanes - chemistry Boronic Acids - chemistry Electrolysis Hydrocarbons, Aromatic - chemistry Hydroxylation Oxidation-Reduction Superoxides - chemistry |
title | A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere |
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