A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere

A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere

An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (57), p.7203-7205
Hauptverfasser: Jiang, Hao, Lykke, Lennart, Pedersen, Steen Uttrup, Xiao, Wen-Jing, Jørgensen, Karl Anker
Format: Artikel
Sprache:eng
Schlagworte:
Alkanes - chemistry
Boronic Acids - chemistry
Electrolysis
Hydrocarbons, Aromatic - chemistry
Hydroxylation
Oxidation-Reduction
Superoxides - chemistry
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Zusammenfassung:An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc32711b