Identification of discharge zones and quantification of contaminant mass discharges into a local stream from a landfill in a heterogeneous geologic setting

► We identified groundwater discharge zones in a local stream in heterogeneous geologic settings. ► Study was downscaled from the landfill to the streambed i.e. sand lenses of clay till. ► We estimated mass discharge of landfill leachate contaminants through the lenses. ► Its ratio to intrinsic mass discharge in the stream is estimated as inconsiderable. ► Seasonal variation of stream hydrology can alter the ratio to a significant value. Contaminants from Risby Landfill (Denmark) are expected to leach through the underlying geologic strata and eventually reach the local Risby Stream. Identification of the groundwater discharge zone was conducted systematically by an array of methods including studies on site geology and hydrogeology, ground- and surface water flows and landfill leachate tracing from April 2009 to December 2010. Chemical profiling by driven wells and gradients in streambed temperatures was an efficient method to identify the contaminant discharge area. A considerable variation of leachate indicators, redox parameters and xenobiotic organic compounds were revealed in this area because of a complex geological setting with clay till (interbedded sand lenses) and deposits of sand and peat. Concentrations of leachate indicators decreased from the landfill to the stream, implying attenuation processes. Xenobiotic organic compounds were mainly phenoxy acid herbicides, while petroleum hydrocarbons and chlorinated solvents were found at very few boreholes. Findings of putative metabolites of phenoxy acid herbicides suggest degradation under the anaerobic conditions, which dominated inside and beneath the landfill. The groundwater discharge was quantified by two methods: direct collection of discharged groundwater by seepage meters and calculations from measurement of streambed temperature gradients. The landfill impacted the stream seasonally during dry periods when concentrations in the stream reached groundwater concentration levels. A comparison between mass balance for selected stream stretches and upscaled measurements of the contaminant discharge from groundwater into the stream indicated that only a small part of the actual contaminant discharge of the stream could be explained by the inflowing contaminant discharge from groundwater. Surface runoff and seepage from ponds along the stream impacted by landfill interflow may be important pathways as well. The placement of Risby Landfill near a stream and the complex source and geology causing a