Gold-Catalyzed Simultaneous Formation of C–C, CO, and C–F bonds in the Presence of Selectfluor: A Synthesis of Fluoroindenes from Allene Esters

Gold-Catalyzed Simultaneous Formation of C–C, CO, and C–F bonds in the Presence of Selectfluor: A Synthesis of Fluoroindenes from Allene Esters

An approach for the synthesis of fluorinated indene derivatives has been developed via a gold-catalyzed three-component tandem reaction between allene esters, Selectfluor, and water.

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Veröffentlicht in:Journal of organic chemistry 2012-06, Vol.77 (12), p.5411-5417
Hauptverfasser: Liu, Yunkui, Zhu, Jie, Qian, Jianqiang, Xu, Zhenyuan
Format: Artikel
Sprache:eng
Schlagworte:
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Catalysis
Chemistry
Cyclization
Diazonium Compounds - chemistry
Esters
Exact sciences and technology
Gold - chemistry
Halogenation
Indenes - chemical synthesis
Indenes - chemistry
Molecular Structure
Organic chemistry
Preparations and properties
Stereoisomerism
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Beschreibung
Zusammenfassung:An approach for the synthesis of fluorinated indene derivatives has been developed via a gold-catalyzed three-component tandem reaction between allene esters, Selectfluor, and water.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo3006528