Cyclic and polycyclic tellurium-tin and tellurium-lead compounds--synthesis, structures and thermal decomposition

The miscellaneously substituted silyltellanes tBu(2)PhSiTeSiMe(3) (1) and (Me(3)Si)(3)SiTeSiMe(3) were used to synthesize the cyclic tin(II) and lead(II) tellurolates [(tBu(2)PhSiTe)(4)M(2)] (M = Sn (2), Pb (3)), [tBu(2)PhSiTePbC(SiMe(3))(3)](2) (4) and the uncommon cluster compound [{(Me(3)Si)(3)Si...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-07, Vol.48 (55), p.6984-6986
Hauptverfasser: Traut, Stephan, von Hänisch, Carsten, Hähnel, Alexander Peter, Stahl, Sven
Format: Artikel
Sprache:eng
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Zusammenfassung:The miscellaneously substituted silyltellanes tBu(2)PhSiTeSiMe(3) (1) and (Me(3)Si)(3)SiTeSiMe(3) were used to synthesize the cyclic tin(II) and lead(II) tellurolates [(tBu(2)PhSiTe)(4)M(2)] (M = Sn (2), Pb (3)), [tBu(2)PhSiTePbC(SiMe(3))(3)](2) (4) and the uncommon cluster compound [{(Me(3)Si)(3)SiTe}(4)Te(2)Sn(4)] (5).
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc32615a