Towards enhancing light harvesting-subphthalocyanines as electron acceptors

One carbon atom is too many. Two subphthalocyanine-extended TTF electron donor-acceptor conjugates were synthesized and characterized. Their photophysical properties prompt the remarkable impact that one extra carbon between the two constitutents exerts on photoinduced processes, that is, charge rec...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (41), p.4953-4955
Hauptverfasser: Romero-Nieto, Carlos, Medina, Anaïs, Molina-Ontoria, Agustin, Claessens, Christian G, Echegoyen, Luis, Martín, Nazario, Torres, Tomás, Guldi, Dirk M
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Sprache:eng
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Zusammenfassung:One carbon atom is too many. Two subphthalocyanine-extended TTF electron donor-acceptor conjugates were synthesized and characterized. Their photophysical properties prompt the remarkable impact that one extra carbon between the two constitutents exerts on photoinduced processes, that is, charge recombination dynamics in the normal versus inverted region.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc31167d