Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cation...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010, Vol.46 (27), p.4962-4964
Hauptverfasser: Dietzel, Pascal D. C., Georgiev, Peter A., Eckert, Juergen, Blom, Richard, Strässle, Thierry, Unruh, Tobias
Format: Artikel
Sprache:eng
Schlagworte:
Analogs
Cations
Cobalt
Magnesium
Metal-organic frameworks
Nickel
Unsaturated
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Beschreibung
Zusammenfassung:Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc00091d