Silver(I)-catalyzed carboxylation of arylboronic esters with CO2

A variety of arylboronic esters were efficiently carboxylated with CO(2) using a simple AgOAc/PPh(3) catalyst, affording the corresponding carboxylic acids in good yield. This simple and efficient silver(i) catalytic system showed wide functional group compatibility.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2012-06, Vol.48 (50), p.6292-6294
Hauptverfasser:	Zhang, Xiao, Zhang, Wen-Zhen, Shi, Ling-Long, Guo, Chun-Xiao, Zhang, Ling-Ling, Lu, Xiao-Bing
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates - chemistry Boronic Acids - chemistry Carbon Dioxide - chemistry Carboxylic Acids - chemical synthesis Carboxylic Acids - chemistry Catalysis Esters - chemistry Organophosphorus Compounds - chemistry Silver Compounds - chemistry
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Beschreibung
Zusammenfassung:	A variety of arylboronic esters were efficiently carboxylated with CO(2) using a simple AgOAc/PPh(3) catalyst, affording the corresponding carboxylic acids in good yield. This simple and efficient silver(i) catalytic system showed wide functional group compatibility.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c2cc32045b