Defect topologies in a nematic liquid crystal near a patchy colloid
Using isothermal-isobaric Monte Carlo simulations we investigate defect topologies due to a spherical colloidal particle immersed in a nematic liquid crystal. Defects arise because of the competition between the preferential orientation at the colloid's surface and the far-field director \docum...
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Veröffentlicht in: | The Journal of chemical physics 2012-05, Vol.136 (19), p.194703-194703-13 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Using isothermal-isobaric Monte Carlo simulations we investigate defect topologies due to a spherical colloidal particle immersed in a nematic liquid crystal. Defects arise because of the competition between the preferential orientation at the colloid's surface and the far-field director
\documentclass[12pt]{minimal}\begin{document}$\widehat{\bm {n}}_{0}$\end{document}
n
̂
0
. Considering a chemically homogeneous colloid as a special case we observe the well-known surface and saturn ring defect topologies for weak and strong perpendicular anchoring, respectively; for homogeneous, strong parallel anchoring we find a boojum defect topology that has been seen experimentally
[see
P. Poulin
and
D. A. Weitz
,
Phys. Rev. E
57
,
626
(
1998
)]
but not in computer simulations. We also consider a heterogeneous, patchy colloid where the liquid-crystal molecules anchor either preferentially planar or perpendicular at the surface of the colloid. For a patchy colloid we observe a boojum ring defect topology in agreement with recent experimental studies
[see
M. Conradi
,
M. Ravnik
,
M. Bele
,
M. Zorko
,
S. Žumer
, and
I. Muševič
,
Soft Matter
5
,
3905
(
2009
)]
. We also observe two other novel defect topologies that have not been reported thus far neither experimentally nor theoretically. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.4717619 |