Reactivity of phosphonodithioato-dppt Ni(II) mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion

Reactivity of phosphonodithioato-dppt Ni(II) mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion

The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-06, Vol.41 (22), p.6611-6613
Hauptverfasser: Aragoni, M Carla, Arca, Massimiliano, Coles, Susanne L, Devillanova, Francesco A, Hursthouse, Michael B, Isaia, Francesco, Lippolis, Vito
Format: Artikel
Sprache:eng
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Zusammenfassung:The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.
ISSN:1477-9234
DOI:10.1039/c2dt30540b