Preparation of α- and β-d-glucoseptanose pentaacetates

The α- and β-d-glucoseptanose pentaacetates have been prepared by treatment of ethyl 1-thio-β-d-glucoseptanoside tetraacetate with mercury(II) acetate in acetic acid. The solid state structure of the β-isomer has been determined by X-ray diffraction.

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Bibliographische Detailangaben
Veröffentlicht in:	Carbohydrate research 2012-05, Vol.353, p.86-91
Hauptverfasser:	Bhadbhade, Mohan, Craig, Donald C., Ng, Clarence J., Odier, Leon, Stevens, John D.
Format:	Artikel
Sprache:	eng
Schlagworte:	acetates Acetates - chemistry acetic acid Carbohydrates - chemical synthesis Carbohydrates - chemistry d-Glucoseptanose Magnetic Resonance Spectroscopy mercury NMR Septanose compounds Stereoisomerism X-ray crystallography X-Ray Diffraction
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Beschreibung
Zusammenfassung:	The α- and β-d-glucoseptanose pentaacetates have been prepared by treatment of ethyl 1-thio-β-d-glucoseptanoside tetraacetate with mercury(II) acetate in acetic acid. The solid state structure of the β-isomer has been determined by X-ray diffraction.
ISSN:	0008-6215 1873-426X
DOI:	10.1016/j.carres.2012.03.011