Direct Enhancement of Nuclear Singlet Order by Dynamic Nuclear Polarization

Hyperpolarized singlet order is available immediately after dissolution DNP, avoiding need for additional preparation steps. We demonstrate this procedure on a sample of [1,2–13C2]pyruvic acid.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2012-05, Vol.134 (18), p.7668-7671
Hauptverfasser:	Tayler, Michael C. D, Marco-Rius, Irene, Kettunen, Mikko I, Brindle, Kevin M, Levitt, Malcolm H, Pileio, Giuseppe
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Isotopes - chemistry Magnetic Resonance Spectroscopy - methods Models, Molecular Pyruvic Acid - chemistry Quantum Theory
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Hyperpolarized singlet order is available immediately after dissolution DNP, avoiding need for additional preparation steps. We demonstrate this procedure on a sample of [1,2–13C2]pyruvic acid.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja302814e