The Importance of Being Exchanged: [GdIII4MII8(OH)8(L)8(O2CR)8]4+ Clusters for Magnetic Refrigeration
Playing it cool: Almost all of the constituent parts of the complex [LnIII4MII8(OH)8(L)8(O2CR)8]X4, namely the lanthanide ions Ln3+, the transition‐metal ions M2+, the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individua...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-05, Vol.51 (19), p.4633-4636 |
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| container_issue | 19 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Hooper, Thomas N. Schnack, Jürgen Piligkos, Stergios Evangelisti, Marco Brechin, Euan K. |
| description | Playing it cool: Almost all of the constituent parts of the complex [LnIII4MII8(OH)8(L)8(O2CR)8]X4, namely the lanthanide ions Ln3+, the transition‐metal ions M2+, the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individual contributions to the magnetocaloric effect. Example in picture: Gd purple, Cu green, O red, N blue. |
| doi_str_mv | 10.1002/anie.201200072 |
| format | Article |
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| language | eng |
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| source | Wiley-Blackwell Journals |
| subjects | cluster compounds gadolinium magnetic refrigeration magnetocaloric effect transition metals |
| title | The Importance of Being Exchanged: [GdIII4MII8(OH)8(L)8(O2CR)8]4+ Clusters for Magnetic Refrigeration |
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