The Importance of Being Exchanged: [GdIII4MII8(OH)8(L)8(O2CR)8]4+ Clusters for Magnetic Refrigeration

The Importance of Being Exchanged: [GdIII4MII8(OH)8(L)8(O2CR)8]4+ Clusters for Magnetic Refrigeration

Playing it cool: Almost all of the constituent parts of the complex [LnIII4MII8(OH)8(L)8(O2CR)8]X4, namely the lanthanide ions Ln3+, the transition‐metal ions M2+, the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individua...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-05, Vol.51 (19), p.4633-4636
Hauptverfasser: Hooper, Thomas N., Schnack, Jürgen, Piligkos, Stergios, Evangelisti, Marco, Brechin, Euan K.
Format: Artikel
Sprache:eng
Schlagworte:
cluster compounds
gadolinium
magnetic refrigeration
magnetocaloric effect
transition metals
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Beschreibung
Zusammenfassung:Playing it cool: Almost all of the constituent parts of the complex [LnIII4MII8(OH)8(L)8(O2CR)8]X4, namely the lanthanide ions Ln3+, the transition‐metal ions M2+, the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individual contributions to the magnetocaloric effect. Example in picture: Gd purple, Cu green, O red, N blue.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201200072