Nonlinear refractive index of some anthraquinone dyes in 1294-1b liquid crystal

Third order nonlinear refractive index of three anthraquinone dyes, i.e., Solvent Blue 59, Solvent Blue 35 and Solvent Green 3 doped in 1294-1b nematic liquid crystal (NLC) were studied by the single beam Z-scan technique using a continuous-wave He–Ne laser at 632.8 nm. The negative nonlinear refractive index (n 2) in the order of 10 − 5 cm 2/w for all samples was obtained. We believe that, this large nonlinearity is owing to Janossy effect and the difference in the nonlinear refractive index of our dyes can be described by the structures of dyes and the interactions between dyes and 1294-1b molecules. So as to understand the effect of dye structure on nonlinearity enhancement, the dichroic ratio of these dyes in 1294-1b was measured using polarized spectroscopy.