A Cationic Calcium Hydride Cluster Stabilized by Cyclen-Derived Macrocyclic N,N,N,N Ligands
Cationic calcium hydride complexes with a [Ca3(μ3‐H)2] core were prepared from different organocalcium precursors and Ph2SiH2. The hydride complexes were found to be active in the catalytic hydrosilylation and hydrogenation of 1,1‐diphenylethene.
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-04, Vol.51 (18), p.4452-4455 |
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| container_issue | 18 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Jochmann, Phillip Davin, Julien P. Spaniol, Thomas P. Maron, Laurent Okuda, Jun |
| description | Cationic calcium hydride complexes with a [Ca3(μ3‐H)2] core were prepared from different organocalcium precursors and Ph2SiH2. The hydride complexes were found to be active in the catalytic hydrosilylation and hydrogenation of 1,1‐diphenylethene. |
| doi_str_mv | 10.1002/anie.201200690 |
| format | Article |
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| ispartof | Angewandte Chemie International Edition, 2012-04, Vol.51 (18), p.4452-4455 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | Wiley Online Library |
| subjects | alkaline earth metals calcium homogeneous catalysis hydrides hydrogen storage |
| title | A Cationic Calcium Hydride Cluster Stabilized by Cyclen-Derived Macrocyclic N,N,N,N Ligands |
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